Solution Chemistry of Surfactants: Volume 1 by E. Tomlinson, S. S. Davis, G. I. Mukhayer (auth.), K. L.

By E. Tomlinson, S. S. Davis, G. I. Mukhayer (auth.), K. L. Mittal (eds.)

The 52nd Colloid and floor technological know-how Symposium of the Divis­ ion of Colloid and floor Chemistry of the yank Chemical Society used to be held in Knoxville, TN, June 12-14, 1978, and one among its Sections was once dedicated to the subject of resolution Chemistry of Surfactants. even though it used to be billed because the part on resolution Chemistry of Surfactants, however it was once certainly a veritable inter­ nationwide symposium in this subject as fifty one papers by way of approximately a hundred con­ tributors from 12 international locations have been indexed within the application. the current quantity and its significant other quantity 2 record the lawsuits of the above-mentioned part on resolution Chemistry of Surfactants. In 1976 there has been held a global symposium on Micellization, Solubilization and Microemulsions in Albany, l the complaints of that have been chronicled in volumes. loads of fabric facing micelles contributed by means of a legion of well-known researchers constitutes those volumes yet a couple of subtopics weren't competently lined; so it was once deemed appro­ priate to hide those issues in addition to the new growth within the normal quarter of aggregation of surfactants during this part. additionally because it is the amphiphilicity or amphipathicity* of a surfact­ ant molecule that is chargeable for either adsorption at inter­ faces and aggregation in resolution, so it used to be thought of fairly apropos to incorporate the subject of adsorption at interfaces during this part. Concomitantly, the current volumes not just disguise the aggregation phenomena but additionally the adsorption at interfaces.

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Solution Chemistry of Surfactants: Volume 1

The 52nd Colloid and floor technological know-how Symposium of the Divis­ ion of Colloid and floor Chemistry of the yank Chemical Society used to be held in Knoxville, TN, June 12-14, 1978, and one in every of its Sections used to be dedicated to the subject of resolution Chemistry of Surfactants. even though it used to be billed because the part on answer Chemistry of Surfactants, however it used to be certainly a veritable inter­ nationwide symposium in this subject as fifty one papers by way of approximately a hundred con­ tributors from 12 international locations have been indexed within the software.

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1 there is a pronounced deviation (Figure 8) from the DebyeHuckel limiting law. Such deviations can be discussed usefully in terms of ion-ion and ion-solvent interactions 34 ,62. It may be argued that the change of solubility product with ionic strength is due to two separate processes. At low ionic strength the activity coefficient will decrease with increased electrolyte content, (as predicted from the Debye-Huckel limiting law). This will thus cause a salting in or increased solubility of the complex.

Oakenfu11 and D. E. Fenwick, Aust. J. , ~, 2649-58 (1973). D. G. Oakenfu11 and D. E. Fenwick, Aust. J. , lL, 2149-57 (1974) • D. G. Oakenfu11 and D. E. Fenwick, J. Phys. , ~, 17591963 (1974). D. G. Oakenfu11 and D. E. Fenwick, Aust. J. , 30, 335-44 (1977) • B. W. Barry and G. M. T. Gray, J. , ~, 327-339 (1975). K. Shinoda, J. Phys. , 58, 541-544 (1954). R. L. Reeves and S. A. Harkaway, in "Mice11ization, Solubilization, and Microemu1sions," K. L. Mitta1, Editor, Vol. 2, p 819, Plenum Press, New York, 1977.

Brown, in Solution Chemistry of Surfactants, K. L. Mitta1, Editor, Vol. 2, pp. 867-868, Plenum Press, 1979. E. Tomlinson and S. S. Davis, J. Pharm. , 28, 75p (1976). S. S. Davis, E. Tomlinson and C. G. Wilson, Brit. J. , In Press (1978). G. H. Nanco11as, "Interactions in Electrolyte Solutions," Elsevier, Amsterdam, 1966. N. Bjerrum, Kg1. Danske Vidensk. Se1skab, 7, 1-48 (1926). S. Petrucci, in "Ionic Interactions," S. Petrucci, Editor, Vol. I, Chap. 3, Academic Press, New York, 1971. A. Werner, Z.

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